Grismar's EVE Wiki : DivisionMissionType

Mission distribution per division

Agents give mixed kill, courier and trade missions, the list below shows a fairly accurate estimate of the distribution. If you want to search for agents working for a division offering a specific mission type, use the EVE Explorer. Set it to 'show agents' and specify 'offering mission of type ..' either 'kill' or 'courier'.

You can also get up to date listings from Q Hegemony, but they do require trust ingame, which can give them information about your current location.

Type	Kill	Courier	Trade	Mining
Accounting	9%	91%	0%	0%
Administration	76%	23%	1%	0%
Advisory	50%	47%	2%	1%
Archives	6%	92%	1%	1%
Astrosurveying	59%	38%	1%	2%
Command	95%	4%	0%	1%
Distribution	15%	84%	1%	0%
Financial	30%	70%	0%	0%
Intelligence	90%	10%	0%	0%
Internal Security	97%	2%	1%	0%
Legal	84%	16%	0%	0%
Manufacturing	9%	85%	3%	3%
Marketing	43%	57%	0%	0%
Mining	25%	44%	3%	28%
Personnel	64%	35%	0%	1%
Production	6%	91%	1%	2%
Public relations	62%	37%	0%	1%
R&D	0%	46%	54%	0%
Security	97%	3%	0%	0%
Storage	18%	80%	2%	0%
Surveillance	93%	6%	1%	0%

Note that R&D missions don't earn you LP or rewards, they just double the RP the agent gets for that day. Also, the requirements to get the R&D agents are special, you need corp standing and skills.

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Current EVE version: 4.10.45943 (Trinity 1.0.1)